tellurium

/te loor"ee euhm/, n. Chem.
a rare, lustrous, brittle, crystalline, silver-white element resembling sulfur in its properties, and usually occurring in nature combined with gold, silver, or other metals of high atomic weight: used in the manufacture of alloys and as a coloring agent in glass and ceramics. Symbol: Te; at. wt.: 127.60; at. no.: 52; sp. gr.: 6.24.
[ < NL (1798), equiv. to L tellur- (s. of tellus) earth + -IUM]

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Introduction
Robert C. Brasted
 semimetallic chemical element in the oxygen group (oxygen group element) (Group 16 [VIa] of the periodic table), closely allied with the element selenium in chemical and physical properties. Tellurium is a silvery-white element with properties intermediate between those of metals and nonmetals; it makes up approximately one part per billion of the Earth's crust. Like selenium, it is less often found uncombined than as compounds of metals such as copper, lead, silver, or gold and is obtained chiefly as a by-product of the refining of copper or lead. No large use for tellurium has been found.

History
      The element tellurium was isolated before it was actually known to be an elemental species. About 1782 Franz Joseph Müller von Reichenstein, an Austrian mineralogist, worked with an ore referred to as German gold. From this ore he obtained a material that defied his attempts at analysis and was called by him metallum problematicum. In 1798 Martin Heinrich Klaproth confirmed Müller's observations and established the elemental nature of the substance. He named the element after man's “heavenly body” Tellus, or Earth.

Occurrence and preparation
      The demand for tellurium does not match that for selenium. The two elements are found together in many ores; they may be isolated by employing the processes described in connection with selenium, obtaining solutions containing salts of both selenious and tellurous acids, H2SeO3 and H2TeO3. Upon treatment of these solutions with sulfuric acid, tellurium dioxide, TeO2, separates because of its low solubility, while the selenious acid remains dissolved. The tellurium dioxide can be converted into elemental tellurium by treatment with sulfur dioxide; an electrolytic process is used to purify the product.

Physical and chemical properties
      In tellurium, the covalent bonding necessary to provide large ring- and chain-molecules by catenation is almost nonexistent. The element crystallizes in the rhombohedral form. It is silvery white and isomorphous with gray selenium—that is, the structure and dimensions of the crystals are very similar. It is brittle but not very hard. The tellurium atoms form spiral chains in the crystal with Te–Te distances of 3.74 Å.

      The element is a poor conductor of heat and only a fair conductor of electricity. Tellurium burns in air or in oxygen with a blue-green flame, forming the dioxide (TeO2). It is unaffected by hydrochloric acid, but either nitric acid or aqua regia (a mixture of nitric acid and hydrochloric acid) oxidizes it to tellurous acid (H2TeO3). It reacts with the halogens (fluorine, chlorine, bromine, and iodine) to form halides, and it combines with most metals at elevated temperatures to form tellurides.

      Although there are adequate supplies of the element, no single use has been developed that creates a large demand for it. Small amounts of tellurium increase the ductility of aluminum alloys, the hardness and tensile strength of tin alloys, and the machinability of stainless steel and copper; in lead and in manganese-magnesium alloys, it increases resistance to corrosion. Bismuth telluride and lead telluride are semiconducting materials that have been used in thermoelectric devices either as sources of electricity or for cooling purposes.

Robert C. Brasted
atomic number
52
atomic weight
127.60
masses of stable isotopes
120, 122, 123, 124, 125, 126, 128, 130
melting point
449.8 °C (841.6 °F)
boiling point
989.9 °C (1,813.8 °F)
oxidation states
−2, +2, +4, +6
electron config.
1s22s22p63s23p63d104s24p64d105s25p4

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Universalium. 2010.

Look at other dictionaries:

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  • Tellurium — Tel*lu ri*um, n. [NL., from L. tellus, uris, the earth.] (Chem.) A rare nonmetallic element, analogous to sulphur and selenium, occasionally found native as a substance of a silver white metallic luster, but usually combined with metals, as with… …   The Collaborative International Dictionary of English

  • Tellurĭum — (lat.), Maschine zur Versinnlichung der bei der täglichen Rotation und dem jährlichen Umlauf der Erde um die Sonne eintretenden Erscheinungen, besonders des durch den Parallelismus der Erdachse bedingten Wechsels der Jahreszeiten. Ein sehr… …   Meyers Großes Konversations-Lexikon

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  • Tellurĭum — Tellurĭum, ein Apparat, durch welchen der Lauf der Erde um die Sonne, u. die Richtung der Erdachse während dieses Laufes, wovon die Jahreszeiten abhängen, so wie der Lauf des Mondes um die Erde dargestellt wird. Zugleich können durch den Apparat… …   Pierer's Universal-Lexikon

  • Tellurium — Tellurĭum (lat.), mechan. Lehrmittel zur Veranschaulichung der Bewegung der Erde um die Sonne …   Kleines Konversations-Lexikon

  • Tellurium — Tellurium, neulat., mechanische Vorrichtung, um die Bewegung der Erde um die Sonne u. die damit zusammenhängenden Erscheinungen zu erklären …   Herders Conversations-Lexikon

  • tellurium — Symbol: Te Atomic number: 52 Atomic weight: 127.60 Silvery metalloid element of group 16. Eight natural isotopes, nine radioactive isotopes. Used in semiconductors and to a degree in some steels. Chemistry is similar to sulphur. Discovered in… …   Elements of periodic system

  • tellurium — metallic element, named by German chemist and mineralogist Martin Heinrich Klaproth (1743 1817) from L. tellus (gen. telluris) earth (see TELLURIAN (Cf. tellurian)) …   Etymology dictionary

  • tellurium — [te loor′ē əm, təlo͞or′ē əm] n. [ModL: coined (1798) by M. H. Klaproth (1743 1817), Ger chemist, for element discovered (1783) by F. J. M. von Reichenstein, Austrian mineralogist < L tellus, earth (see TELLURIAN) + IUM, in contrast to URANIUM] …   English World dictionary

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